I have a 454 big block, so not quite the same starting point and more challenges with clearance to the bonnet to worry about.
I am in the process of having a Holley Double Pumper carb fitted and tuned, along with a GM LS6 aluminium air intake manifold and new air filter, replacing the original cast iron intake, Rochester quadrajet carb and twin snorkel air filter. Paul at Lincolnshire Corvette is working on this for me and is doing a great job - really happy with the progress being made and work done.
My original carb had a built-in choke mechanism, and the new carb needs either a manual choke cable or an electronic choke controller, so not a simple direct replacement. There are also potential issues with the fuel pipe to overcome and clearance issues for the throttle linkage and filter housing from what I have read.
So far the differences in performance are very good and worth every penny, and I expect there is still some optimisation to be had here when the car goes back for the final bits of work.
EMC(Gavin) is also a bit of a legend and would definitely be able to advise on how simple the change is likely to be. I would strongly recommend you take his offer of a call up.